Policy Issues in U.S. Transportation Public-Private Partnerships: Lessons from Australia, Research Report 09-15

In this report, the authors examine Australia’s experience with transportation public-private partnerships (PPPs) and the lessons that experience holds for the use of PPPs in the United States. Australia now has decades of experience in PPP use in transportation, and has used the approach to deliver billions of dollars in project value. Although this report explores a range of issues, the authors focus on four policy issues that have been salient in the United States: (1) how the risks inherent in PPP contracts should be distributed across public and private sector partners; (2) when and how to use non-compete (or compensation) clauses in PPP contracts; (3) how concerns about monopoly power are best addressed; and (4) the role and importance of concession length. The study examines those and other questions by surveying the relevant literature on PPP international use. The authors also interviewed 23 Australian PPP experts from the academic, public and private sectors, and distilled lessons from those interviews

The US Transit Bus Manufacturing Industry

Manufacturing buses for the US transit market has been a challenging business over the last several decades. It is a small market with volatile demand. Many manufacturers have gone bankrupt, left the market, or been acquired by competitors. Manufacturers of transit buses in the US must comply with a wide range of operational and design regulations. The most salient policy areas include regulating emissions, disabled access, procurement, alternative fuels, the Altoona Test, pooled purchases and piggybacking, spare ratios, workforce training, minimum useful life, Buy America, and research & development (R&D). The purpose of this report is to provide policy makers with an update on the state of the industry, an analysis of how government policies are impacting the industry, and suggestions for policies that can help the industry move forward and thrive to best serve the transit-riding public

f-Element Electrochemistry in Room Temperature Ionic Liquids

This proposal focuses on f-element electrochemistry in room temperature ionic liquids (RTILs). The ultimate goal is to fully characterize the oxidation/reduction of elements in RTILs to establish the baseline thermodynamic and kinetic data for these systems. The data will be used to critically evaluate the ability to use electrochemical methods for controlled, potential mediated, separation off-elements by electroplating on electrodes surfaces. Factors that will influence the ability to measure the redox processes in f-elements in RTIL solutions and electroplating on electrode surfaces include the structure, solubility, and stability of the target species in these solutions. These factors will be addressed using a multidisciplinary research approach with techniques including UV/Vis, and FTIR spectroscopy which will provide structural and stability information. These studies will provide a comprehensive study of the use of RTIL systems in the electrochemical analysis and potential dependent separation of f-elements by electroplating. This research will address the need to demonstrate, by 2015, progress in understanding, modeling and controlling chemical reactivity and energy transfer processes in solutions at electrochemical interfaces using non-aqueous solutions comprised entirely of organic cations and inorganic/organic anions. Electrochemical studies will examine the interfacial electron transfer processes of f-elements and the potential dependent deposition of f-elements at electrode surfaces. These studies will probe the ability to use RTIL systems in the controlled, potential dependent, separation of f-elements species from complex mixtures

Electrochemical Separation of Curium and Americium

The objective of this project is to develop a method for the separation of Am from Cm based on electrochemical techniques. Electrochemical systems that allow the thermodynamics of actinide and lanthanide complexes to be systematically evaluated and tuned will be examined. The influence of complex formation on the ability to selectively isolate a given species electrochemically will be evaluated. Metal-ligand complex formation provides a useful derivation technique to increase solubility in solution environments that favor precipitation. In addition, the thermodynamic properties of a complex relative to the isolated species may be shifted to more suitably measurable electrochemical separation regimes. Electrochemical sorption methods are well suited for use in the separation of similar chemical species where the applied potential provides the thermodynamic selectivity required. Traditional separation techniques will be evaluated using common electrodes such as Hg, Au/Hg film, and glassy carbon. In addition, conductive polymer such as polypyrrole will examined to provide a more novel method of separating and sequestering of actinide and lanthanide chemical species. The polymer composite electrodes will be chemically modified with chelating and the separation of chemical species based on the adsorption/desorption thermodynamics of the polymer relative to the complex or isolate species will be probed. The proposed experiments will provide a comprehensive survey of the effect of complex formation and species on the ability to separate complex mixtures of actinide and lanthanide complexes in aqueous environments using electrochemical methods and modified polymer electrodes. Year one of the project will develop the lab facilities required for the electrochemical experiments. The electrochemical workstation will be acquired and necessary electrodes, reagents, and supplies will be purchased. The year one goals are to prepare and electrochemically evaluate the complexes and species of interest in this study or species that closely resemble more hazardous counterparts. These studies will be important for the future studies of polypyrrole membranes providing the required thermodynamic data concerning the complexes formed and possible separation of complex mixtures

The Electrochemical Separation of Curium and Americium: Quaterly Report August-December 2004

This research report outlines the current status and progress associated with the electrochemical separation of Curium and Americium. The following pages outline the progress on our project to date. We have been actively performing research on this project for three months and are currently on schedule in terms of the proposed timelines. The initial focus of the project involved setting up the laboratories for the studies outlined in the grant proposal. The instrumentation needed included an electrochemical work station that will perform the bulk of the electrochemical studies. This instrument will complement the electrochemical instrumentation in Dr. Hatchett’s laboratory and will be housed in Dr. Czerwinski’s laboratory. In addition the required electrodes, electrochemical glassware, side apparatus including nitrogen degassers and the chemicals for the initial studies were obtained

The Electrochemical Separation of Curium and Americium: Quaterly Report January - March, 2006

This research report outlines the current status and progress associated with the electrochemical separation of Curium and Americium. For two and a half years, research has been actively performed on this project, and is currently on schedule for the proposed timelines. Progress: • The electrochemical characterization of Ce and Eu complexed with EDTA, NTA, and Citrate has been completed. • Synthesis of the polymer substrate and the chelating ligand is underway. Approximately 50 grams of disulfide has been produced to produce the chelating thiol group required for the last set of studies. • Gold substrates have been prepared to perform the 2-D surface chelation using the chelating disulfide and thiol. The goal is to determine the potentials required for chelation. • Polymer gold composite systems have been prepared and characterized for use with the chelating ligands

Electrochemical Separation of Curium and Americium

The objective of this project is to use electrochemical techniques to develop a thermodynamic understanding of actinide and lanthanide species in aqueous solution and use this data to effectively separate species with very similar chemical properties. In consultation with a national laboratory collaborators, electrochemical methods and materials will be evaluated and used to exploit the thermodynamic differences between similar chemical species enhancing the ability to selectively target and sequester individual species from mixtures. This project is in its third year and has successfully completed Phases 1 and 2. The following were specific goals for this year: To develop a fundamental understanding of the thermodynamic properties of actinide and lanthanide species such as Cm, Am, Ce, Nd, Eu, and Sm after complex formation. To examine how chelation influences the thermodynamic properties of waste form species. To use systematic studies to distinguish the thermodynamic signatures and ability to shift thermodynamic potentials using chelation to enhance separation properties

The Electrochemical Separation of Curium and Americium: Quaterly Report January - March 2004

This research report outlines the current status and progress associated with the electrochemical separation of Curium and Americium. Data collection and analysis of the Ce3+/Ce4+ redox couple in various supporting electrolytes has continued. All electrolyte systems were investigated at Pt, Au, and Glassy Carbon working electrodes. Analysis of these data was accomplished by performing appropriate background subtractions to reveal net peaks due to Ce redox behavior. Successful identification of the Ce redox couple was achieved with all electrolyte/electrode systems, although a decline in peak resolution was observed with increasing acid concentration. Optimal conditions in this experiment were realized with a 6.0 mM Ce concentration, 0.1 M H2SO4 supporting electrolyte, and scan rate of 0.02 V/s. An investigation into ionic strength is being conducted for the Ce system, using varying concentrations of K2SO4 in place of the H2SO4 supporting electrolyte solutions. The data suggests that acidity is the key variable in the system with higher resolution and lower splitting of the Ce3+/Ce4+ redox couple. Finally, the investigation of the Sm redox couple was initiated by employing the conditions determined as optimal for the Ce experiment. Successful resolution of the Sm redox couple was accomplished using this system. Future work on this species will include further experiments, similar to those conducted for Ce, which will vary the working electrode and supporting electrolyte

The Electrochemical Separation of Curium and Americium: Quaterly Report April - June, 2005

This research report outlines the current status and progress associated with the electrochemical separation of Curium and Americium. Results • We have completed the electrochemical investigation in of the Ce3+/Ce4+ redox couple and have determined the optimum experimental conditions. • Computer modeling of the cerium using the JChess speciation-modeling program has been completed for the Ce redox couple. Traditional complexing ligands such as EDTA, oxalate, NTA, phosphate, acetate, and sulfate have been purchased and will be used to initiate the complexation and electrochemical characterization. • Electrochemical investigations have continued on the Eu2+/Eu3+ redox system in HClO4 supporting electrolyte at a glassy carbon working electrode. The redox couple has been electrochemically resolved using cyclic voltammetry and square wave voltammetry. The data suggests that the couple is stable with reversible oxidation/reduction occurring. • Complex formation has been initiated and theoretical calculations regarding the stability of species has been used to target the solution conditions required to view the oxidation/reduction processes